Dichlorido{N-[1-(pyrazin-2-yl)ethylidene-κN1]ethane-1,2-diamine-κ2N,N′}zinc

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Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN 1]ethane-1,2-diamine-κ2 N,N′}zinc

The Zn(II) atom in the title complex, [ZnCl(2)(C(8)H(12)N(4))], is coordinated by two Cl atoms and three N atoms of the N-[1-(pyrazin-2-yl)ethyl-idene]ethane-1,2-diamine ligand, and displays a distorted square-pyramidal geometry with the apical position occupied by a Cl atom. In the crystal, inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds link the mol-ecules into a three-dimensional framework.

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1-[2-(Pyrazin-2-ylsulfan­yl)eth­yl]pyrazine-2(1H)-thione

The title multifunctional twisted organic ligand, C(10)H(10)N(4)S(2), contains a short C=S bond [1.671 (2) Å]. The dihedral angle between the two pyrazine rings is 39.83 (6)°. In the crystal, inter-molecular C-H⋯N and C-H⋯S hydrogen bonds result in the formation of a supra-molecular network.

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2-[(2-Hy­droxy­benz­yl)amino]­pyrazinium perchlorate–2-[(pyrazin-2-yl­amino)­meth­yl]phenol (1/1)

In the crystal structure of the title co-crystal, C(11)H(12)N(3)O(+)·ClO(4) (-)·C(11)H(11)N(3)O, the perchlorate ion is disordered about a twofold rotation axis with the Cl atom located on the twofold rotation axis; the 2-[(2-hy-droxy-benz-yl)amino]-pyrazinium cation and the neutral 2-[(pyrazin-2-yl-amino)-meth-yl]phenol mol-ecule are disordered about the rotation axis in a 1:1 ratio. These two...

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N-(Pyrazin-2-yl)aniline

The two aromatic rings in the title compound, C(10)H(9)N(3), are inclined at 15.2 (1)° to each other; this opens up the angle at the amino N atom to 130.4 (1)°. The amino N atom forms a hydrogen bond to the 4-N atom of an adjacent mol-ecule to create a chain motif.

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Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate

The title compound, C(14)H(14)N(4)S(2), was obtained from a condensation reaction of benzyl dithio-carbazate and acetyl-pyrazine. The asymmetric unit contains two independent mol-ecules, in each of which the pyrazine ring and dithio-carbazate unit are approximately co-planar, the r.m.s. deviations being 0.0304 and 0.0418 Å. The mean plane is oriented with respect to the benzene ring at 49.22 (4...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811042115